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"Elemental Mercury Adsorption and Recovery by Electrothermal Swi

"Elemental Mercury Adsorption and Recovery by Electrothermal Swi」於資料集「EPQSummary_WasteManagement」由單位「行政院環境保護署」的郭先生所提供,聯繫電話是02-2311-7722 EXT.2399,最近更新時間為:2022-01-15 01:13:53。 欄位Project Title的內容是"Elemental Mercury Adsorption and Recovery by Electrothermal Swing System with Gold Electrodeposited Activated Carbon Fiber Cloth" , 欄位Project Subject的內容是"Owing to the high toxicity of mercury (Hg), the restriction of Hg-containing products in different countries is getting rigorous. The huge number of Hg-containing products such as fluorescent lamps of the liquid-crystal displays are discarded and need to be recycled. Because Hg in several commercial products is still indispensable, therefore, it is necessary to remove and recover Hg released during the disassembling process. In this study, activated carbon fiber cloth (ACFC) was produced by Taiwan Carbon Corp., which was used as the raw material (Raw-ACFC). The gold electrodeposited ACFCs (GE-ACFC) were successfully prepared under various electrodeposition periods. Physical and chemical characterizations of Raw-ACFC and GE-ACFC showed that the gold content of GE-ACFC increased with extending electrodeposition periods, nevertheless, the decrease in the pore volume and specific area of GE-ACFC due to pore blockage was also observed. We found that gold modification of ACFC could effectively improve Hg0 adsorption capacity of ACFC, however, the gold content did not always favor the Hg0 adsorption since excessive gold deposition might reduce the contact area between Au and Hg0, compromising Hg0 adsorption capacity of GE-ACFC. Gold-electrodeposited ACFC with the Au growth time of 1200 s (i.e., GE-ACFC-1200s) exhibited the largest Hg0 adsorption capacity. The results obtained from TPD showed that there were two major desorption peaks in Raw-ACFC, indicating Hg0 was physically adsorbed by pore structures and chemically adsorbed by oxygen functional groups. In contrast, the Hg adsorption of GE-ACFC appeared to be controlled by physical adsorption by Au amalgamation. The adsorption efficiency of GE-ACFC-1200s was above 90% and showed a high stability at different regeneration temperatures in 3-cycle electrothermal swing system experiments." , 欄位Project Year的內容是2020 , 欄位Organizer的內容是"Recycling Fund Management Board" , 欄位Executive Unit的內容是"國立臺灣大學" , 欄位Reporting download URL的內容是https://epq.epa.gov.tw , 欄位Publish Date的內容是20210201

Project Title

"Elemental Mercury Adsorption and Recovery by Electrothermal Swing System with Gold Electrodeposited Activated Carbon Fiber Cloth"

Project Subject

"Owing to the high toxicity of mercury (Hg), the restriction of Hg-containing products in different countries is getting rigorous. The huge number of Hg-containing products such as fluorescent lamps of the liquid-crystal displays are discarded and need to be recycled. Because Hg in several commercial products is still indispensable, therefore, it is necessary to remove and recover Hg released during the disassembling process. In this study, activated carbon fiber cloth (ACFC) was produced by Taiwan Carbon Corp., which was used as the raw material (Raw-ACFC). The gold electrodeposited ACFCs (GE-ACFC) were successfully prepared under various electrodeposition periods. Physical and chemical characterizations of Raw-ACFC and GE-ACFC showed that the gold content of GE-ACFC increased with extending electrodeposition periods, nevertheless, the decrease in the pore volume and specific area of GE-ACFC due to pore blockage was also observed. We found that gold modification of ACFC could effectively improve Hg0 adsorption capacity of ACFC, however, the gold content did not always favor the Hg0 adsorption since excessive gold deposition might reduce the contact area between Au and Hg0, compromising Hg0 adsorption capacity of GE-ACFC. Gold-electrodeposited ACFC with the Au growth time of 1200 s (i.e., GE-ACFC-1200s) exhibited the largest Hg0 adsorption capacity. The results obtained from TPD showed that there were two major desorption peaks in Raw-ACFC, indicating Hg0 was physically adsorbed by pore structures and chemically adsorbed by oxygen functional groups. In contrast, the Hg adsorption of GE-ACFC appeared to be controlled by physical adsorption by Au amalgamation. The adsorption efficiency of GE-ACFC-1200s was above 90% and showed a high stability at different regeneration temperatures in 3-cycle electrothermal swing system experiments."

Project Year

2020

Organizer

"Recycling Fund Management Board"

Executive Unit

"國立臺灣大學"

Reporting download URL

https://epq.epa.gov.tw

Publish Date

20210201

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